Synthesis and Structural Characterization of a New 2D Coordination Polymer [Cu(pzta)2]n

A new copper(Ⅱ)tetrazolate coordination polymer[Cu(pzta)2]n (1)(pzta=5-pyrazinyltetrazolate)was prepared from the hydrothermal reaction of Cu(OAc)2,·H2O with NaN3 and pyrazinecarbonitrile(pzCN)in the presence of ethanol,and characterized by elemental analysis,IR,TGA and X-ray crystallography.The X-ray diffraction analysis of 1 shows that the compound crystallizes in the monoclinic system with space group P2(1)/c and Cu(Ⅱ)ion center is six-coordinated by four different pzta ligands.The complex 1 features a 2D tetrazole coordination polymer.The thermal analysis of 1 shows that the decomposition of the complex OCCURS in two regions.

作 者： HU,Xin LIU,Cong WANG,Yongjiang GUO,Jixi   作者單位： HU,Xin,LIU,Cong,WANG,Yongjiang(College of LifeScience & Chemistry,Xinjiang Normal University,Urumqi,Xinjiang 830054,China)

GUO,Jixi(Institute of Applied Chemistry,Xinjiang University,Urumqi,Xinfiang 830046,China) 

刊 名： 中國化學(xué)（英文版）  SCI 英文刊名： CHINESE JOURNAL OF CHEMISTRY  年，卷(期)： 2009 27(3)  分類號： O6  關(guān)鍵詞： Coordination polymer   crystal structure   pyrazinecarbonitrile   hydrothermal reaction  

【Synthesis and Structural Characteriz】相關(guān)文章：

Synthesis of 4-Aminosalicylglycine04-26

Study on synthesis of polylactide from kitchen garbage04-25

Synthesis of nanosize MnO2 and its performence04-27

Synthesis and Crystal Structure of Binuclear Copper(Ⅱ)Complex Containing (Dimethylaminomethyl)ferrocene04-27

Comparison of seismic actions and structural design requirements in Chinese Code GB 50011 and International Standard ISO04-27

Enhanced activity of yqhD oxidoreductase in synthesis of 1,3-propanediol by error-prone PCR04-26

Synthesis and Crystal Structure of 1,4-Bis(2-hydroxymethylphenyl)-1,4-dioxabutane04-27

Synthesis and Crystal Structure of N,N-Diphenyl-3,6-diethyl-1,4-dihydro-s-tetrazine-1,4-dicarbonamide04-26

Synthesis and Crystal Structure of 1-(Trifluoromethyl)-1-(propioloyl)-(E)-3-oxo-(2-thienyl)-(2-naphthylamine)04-26

Synthesis and Structure of [Cu2(μ-NO2)(aepy)4](ClO4)3 (aepy = 2-(2-Aminoethyl)pyridine)04-27